混合价化合物的合成及其分子内金属间电子转移
研究员，博士生导师。2002年12月德国弗莱堡(Freiburg)大学获博士学位；2003年1月至2004年3月，德国哥廷根(Goettingen)大学博士后。2004年4月至2005年6月，南昌大学化学系教授；2005年7月起,中国科学院福建物质结构研究所吴新涛院士组工作。主要研究兴趣聚焦于混合价化合物的合成及其分子内金属间电子转移，旨在以混合价单分子化合物为简单模型，通过深入研究其金属间电子转移及电子离域性质，揭示存在于自然界及生物体中复杂的电子转移机制，以期能对分子导线、分子开关等分子电子器件的制备提供有价值的理论指导。
1、Jin-Hui Fu, Zi-Hang Wu, Ying Song, Bing-Chang Tan, Xin-Tao Wu and Tian-Lu Sheng*, "Protonation-Induced Reversible Switching of Electronic Delocalization in a Linear Ru-Ru-Ru Complex", Chem. Eur. J. 2025, 31, e202500617.
2、Xiao-Lin Liu, Yi Li, Hao Wang, Yu-Ying Yang, Han Liu, Xin-Tao Wu and Tian-Lu Sheng*, "Chain-like Pentanuclear Complexes: Syntheses, Crystal Structures and Long-range Electronic Interactions of Cyanido-Bridged M2Ru3 (M = Fe, Ru)", Chem. Eur. J. 2024, 30, e202402771.
3、Chen Zeng, Qing-Dou Xu, Xiao-Lin Liu, Yu-Ying Yang, Sheng-Min Hu, Xin-Tao Wu and Tian-Lu Sheng*, "Metal-metal charge transfer properties of a series of trinuclear Fe2Ru and corresponding pentanuclear Fe2Ru2Ag cyanido-bridged complexes", Chem. Eur. J. 2023, 29, e202300433.
4、Yong He, Ying-Ying Huang, Xiao-Quan Zhu, Jin-Hui Fu, Xin-Tao Wu and Tian-Lu Sheng*, "Coexistence of Three Different Spin States in a Cyanido-Bridged Trinuclear Iron(III) Complex with an Unusual FeIII to Ligand Charge Transfer ", Chem. Eur. J. 2023, 29, e202300100.
5、Xiao-Lin Liu, Yi Li, Qing-Dou Xu, Yu-Ying Yang, Jin-Hui Fu, Xin-Tao Wu, Tian-Lu Sheng*, "Influence of the CN Orientation on the Degree of Electron Delocalization of Ru−Ru−Ru Mixed-Valent Complexes", Inorg. Chem. 2022, 61, 17392−17401.
6、Yu-Ying Yang#, Xiao-Quan Zhu#, Jean-Pierre Launay, Cheng-Bin Hong, Shao-Dong Su, Yue-Hong Wen, Xin-Tao Wu and Tian-Lu Sheng*, "Electron Transfer Process in Mixed Valence Compounds with Low-lying Energy Bridge in Different Oxidation States", Angew. Chem. Int. Ed.，2021, 60, 4804-4814.
7、Shao-Dong Su, Xiao-Quan Zhu,Yue-Hong Wen, Lin-Tao Zhang,Yu-Ying Yang,Chen-Sheng Lin*, Xin-Tao Wuand Tian-Lu Sheng*, "A Diruthenium-Based Mixed Spin Complex Ru25+ (S=1/2)-CN-Ru25+ (S=3/2)", Angew. Chem. Int. Ed.，2019,58, 15344-15348.
8、Yu-Ying Yang, Xiao-Quan Zhu, Sheng-Min Hu, Shao-Dong Su, Lin-Tao Zhang, Yue-Hong Wen, Xin-Tao Wu and Tian-Lu Sheng*, "Different Degrees of Electron Delocalization in Mixed Valence Ru-Ru-Ru Compounds by Cyanido-/Isocyanido-Bridge Isomerism", Angew. Chem. Int. Ed.，2018,57, 14046-14050.
9、Xiao Ma, Chen-Sheng Lin, Xiao-Quan Zhu, Sheng-Min Hu, Tian-Lu Sheng*, and Xin-Tao Wu, "An Unusually Delocalized Mixed-Valence State of a Cyanidometal-Bridged Compound Induced by Thermal Electron Transfer ", Angew. Chem. Int. Ed.，2017，56，1605–1609.
10、Xiao Ma, Chen-Sheng Lin, Sheng-Min Hu, Chun-Hong Tan, Yue-Hong Wen, Tian-Lu Sheng*, and Xin-Tao Wu, "Influence of Central Metalloligand Geometry on Electronic Communication between Metals: Syntheses, Crystal Structures, MMCT Properties of Isomeric Cyanido-Bridged Fe2Ru Complexes, and TDDFT Calculations", Chem. Eur. J., 2014, 20, 7025 – 7036 (获Chemistry views专题评述）
研究员